Given the remarkable success that large visual language models (LVLMs) have achieved in image perception tasks, the endeavor to make LVLMs perceive the world like humans is drawing increasing attention. Current multi-modal benchmarks primarily focus on facts or specific topic-related knowledge contained within individual images. However, they often overlook the associative relations between multiple images, which require the identification and analysis of similarities among entities or content present in different images. Therefore, we propose the multi-image relation association task and a meticulously curated Multi-granularity Multi-image Relational Association (MMRA) benchmark, comprising 1,024 samples. In order to systematically and comprehensively evaluate current LVLMs, we establish an associational relation system among images that contain 11 subtasks (e.g, UsageSimilarity, SubEvent) at two granularity levels (i.e., image and entity) according to the relations in ConceptNet. Our experiments reveal that on the MMRA benchmark, current multi-image LVLMs exhibit distinct advantages and disadvantages across various subtasks. Notably, fine-grained, entity-level multi-image perception tasks pose a greater challenge for LVLMs compared to image-level tasks. Moreover, LVLMs perform poorly on spatial-related tasks, indicating that LVLMs still have limited spatial awareness. Additionally, our findings indicate that while LVLMs demonstrate a strong capability to perceive image details, enhancing their ability to associate information across multiple images hinges on improving the reasoning capabilities of their language model component. Moreover, we explored the ability of LVLMs to perceive image sequences within the context of our multi-image association task. Our experiments show that the majority of current LVLMs do not adequately model image sequences during the pre-training process.