Preference learning is critical for aligning large language models (LLMs) with human values, yet its success hinges on high-quality datasets comprising three core components: Preference \textbf{A}nnotations, \textbf{I}nstructions, and \textbf{R}esponse Pairs. Current approaches conflate these components, obscuring their individual impacts and hindering systematic optimization. In this work, we propose \textbf{AIR}, a component-wise analysis framework that systematically isolates and optimizes each component while evaluating their synergistic effects. Through rigorous experimentation, AIR reveals actionable principles: annotation simplicity (point-wise generative scoring), instruction inference stability (variance-based filtering across LLMs), and response pair quality (moderate margins + high absolute scores). When combined, these principles yield +5.3 average gains over baseline method, even with only 14k high-quality pairs. Our work shifts preference dataset design from ad hoc scaling to component-aware optimization, offering a blueprint for efficient, reproducible alignment.