Unified Structured Knowledge Reasoning (USKR) aims to answer natural language questions (NLQs) by using structured sources such as tables, databases, and knowledge graphs in a unified way. Existing USKR methods either rely on employing task-specific strategies or custom-defined representations, which struggle to leverage the knowledge transfer between different SKR tasks or align with the prior of LLMs, thereby limiting their performance. This paper proposes a novel USKR framework named \textsc{Pandora}, which takes advantage of \textsc{Python}'s \textsc{Pandas} API to construct a unified knowledge representation for alignment with LLM pre-training. It employs an LLM to generate textual reasoning steps and executable Python code for each question. Demonstrations are drawn from a memory of training examples that cover various SKR tasks, facilitating knowledge transfer. Extensive experiments on four benchmarks involving three SKR tasks demonstrate that \textsc{Pandora} outperforms existing unified frameworks and competes effectively with task-specific methods.