Processing structured tabular data, particularly lengthy tables, constitutes a fundamental yet challenging task for large language models (LLMs). However, existing long-context benchmarks primarily focus on unstructured text, neglecting the challenges of long and complex structured tables. To address this gap, we introduce NeedleInATable (NIAT), a novel task that treats each table cell as a "needle" and requires the model to extract the target cell under different queries. Evaluation results of mainstream LLMs on this benchmark show they lack robust long-table comprehension, often relying on superficial correlations or shortcuts for complex table understanding tasks, revealing significant limitations in processing intricate tabular data. To this end, we propose a data synthesis method to enhance models' long-table comprehension capabilities. Experimental results show that our synthesized training data significantly enhances LLMs' performance on the NIAT task, outperforming both long-context LLMs and long-table agent methods. This work advances the evaluation of LLMs' genuine long-structured table comprehension capabilities and paves the way for progress in long-context and table understanding applications.