In many face recognition applications, there is large amount of face data with two images for each person. One is an ID photo for face enrollment, and the other is a probe photo captured on spot. Most existing methods are designed for training data with limited breadth (relatively small class number) and sufficient depth (many samples for each class). They would meet great challenges when applied on this ID vs. Spot (IvS) data, including the under-represented intra-class variations and the excessive demand on computing devices. In this paper, we propose a deep learning based large-scale bisample learning (LBL) method for IvS face recognition. To tackle the bisample problem that there are only two samples for each class, a classification-verification-classification (CVC) training strategy is proposed to progressively enhance the IvS performance. Besides, a dominant prototype softmax (DP-softmax) is incorporated to make the deep learning applicable on large-scale classes. We conduct LBL on a IvS face dataset with more than two million identities. Experimental results show the proposed method achieves superior performance than previous ones, validating the effectiveness of LBL on IvS face recognition.