In this paper, we explored how to boost speech emotion recognition (SER) with the state-of-the-art speech pre-trained model (PTM), data2vec, text generation technique, GPT-4, and speech synthesis technique, Azure TTS. First, we investigated the representation ability of different speech self-supervised pre-trained models, and we found that data2vec has a good representation ability on the SER task. Second, we employed a powerful large language model (LLM), GPT-4, and emotional text-to-speech (TTS) model, Azure TTS, to generate emotionally congruent text and speech. We carefully designed the text prompt and dataset construction, to obtain the synthetic emotional speech data with high quality. Third, we studied different ways of data augmentation to promote the SER task with synthetic speech, including random mixing, adversarial training, transfer learning, and curriculum learning. Experiments and ablation studies on the IEMOCAP dataset demonstrate the effectiveness of our method, compared with other data augmentation methods, and data augmentation with other synthetic data.