Sixth-generation (6G) networks are poised to revolutionize communication by exploring alternative spectrum options, aiming to capitalize on strengths while mitigating limitations in current fifth-generation (5G) spectrum. This paper explores the potential opportunities and emerging trends for cmWave and sub-THz spectra as key radio enablers. This paper poses and answers three key questions regarding motivation of additional spectrum to explore the strategic implementation and benefits of cmWave and sub-THz spectra. Also, we show using case studies how these complementary spectrum bands will enable new applications in 6G, such as integrated sensing and communication (ISAC), re-configurable intelligent surfaces (RIS) and non-terrestrial networks (NTN). Numerical simulations reveal that the ISAC performance of cmWave and sub-THz spectra outperforms that of existing 5G spectrum, including sub-6 GHz and mmWave. Additionally, we illustrate the effective interplay between RIS and NTN to counteract the effects of high attenuation at sub-THz frequencies. Finally, ongoing standardization endeavors, challenges and promising directions are elucidated for these complementary spectrum bands.