This paper overviews certain radiation detection, perception, and planning challenges for nuclearized robotics that aim to support the waste management and decommissioning mission. To enable the autonomous monitoring, inspection and multi-modal characterization of nuclear sites, we discuss important problems relevant to the tasks of navigation in degraded visual environments, localizability-aware exploration and mapping without any prior knowledge of the environment, as well as robotic radiation detection. Future contributions will focus on each of the relevant problems, will aim to deliver a comprehensive multi-modal mapping result, and will emphasize on extensive field evaluation and system verification.