With the release of GPT-4V(O), its use in generating pseudo labels for multi-modality tasks has gained significant popularity. However, it is still a secret how to build such advanced models from its base large language models (LLMs). This work explores the potential of using LLMs alone for data generation and develop competitive multi-modality models focusing on chart understanding. We construct a large-scale chart dataset, SynChart, which contains approximately 4 million diverse chart images with over 75 million dense annotations, including data tables, code, descriptions, and question-answer sets. We trained a 4.2B chart-expert model using this dataset and achieve near-GPT-4O performance on the ChartQA task, surpassing GPT-4V.