Semantic segmentation of remote sensing images plays a vital role in a wide range of Earth Observation (EO) applications, such as land use land cover mapping, environment monitoring, and sustainable development. Driven by rapid developments in Artificial Intelligence (AI), deep learning (DL) has emerged as the mainstream tool for semantic segmentation and achieved many breakthroughs in the field of remote sensing. However, the existing DL-based methods mainly focus on unimodal visual data while ignoring the rich multimodal information involved in the real world, usually demonstrating weak reliability and generlization. Inspired by the success of Vision Transformers and large language models, we propose a novel metadata-collaborative multimodal segmentation network (MetaSegNet) that applies vision-language representation learning for semantic segmentation of remote sensing images. Unlike the common model structure that only uses unimodal visual data, we extract the key characteristic (i.e. the climate zone) from freely available remote sensing image metadata and transfer it into knowledge-based text prompts via the generic ChatGPT. Then, we construct an image encoder, a text encoder and a crossmodal attention fusion subnetwork to extract the image and text feature and apply image-text interaction. Benefiting from such a design, the proposed MetaSegNet demonstrates superior generalization and achieves competitive accuracy with state-of-the-art semantic segmentation methods on the large-scale OpenEarthMap dataset (68.6% mIoU) and Potsdam dataset (93.3% mean F1 score) as well as LoveDA dataset (52.2% mIoU).