Directional scanning sounding (DSS) has become widely adopted for high-frequency channel measurements because it effectively compensates for severe path loss. However, the resolution of existing multipath component (MPC) angle estimation methods is constrained by the DSS angle sampling interval. Therefore, this communication proposes a high-resolution MPC angle estimation method based on power-angle-delay profile (PADP) for DSS. By exploiting the mapping relationship between the power difference of adjacent angles in the PADP and MPC offset angle, the resolution of MPC angle estimation is refined, significantly enhancing the accuracy of MPC angle and amplitude estimation without increasing measurement complexity. Numerical simulation results demonstrate that the proposed method reduces the mean squared estimation errors of angle and amplitude by one order of magnitude compared to traditional omnidirectional synthesis methods. Furthermore, the estimation errors approach the Cram\'er-Rao Lower Bounds (CRLBs) derived for wideband DSS, thereby validating its superior performance in MPC angle and amplitude estimation. Finally, experiments conducted in an indoor scenario at 37.5 GHz validate the excellent performance of the proposed method in practical applications.