Visually-Rich Document Entity Retrieval (VDER) is a type of machine learning task that aims at recovering text spans in the documents for each of the entities in question. VDER has gained significant attention in recent years thanks to its broad applications in enterprise AI. Unfortunately, as document images often contain personally identifiable information (PII), publicly available data have been scarce, not only because of privacy constraints but also the costs of acquiring annotations. To make things worse, each dataset would often define its own sets of entities, and the non-overlapping entity spaces between datasets make it difficult to transfer knowledge between documents. In this paper, we propose a method to collect massive-scale, noisy, and weakly labeled data from the web to benefit the training of VDER models. Such a method will generate a huge amount of document image data to compensate for the lack of training data in many VDER settings. Moreover, the collected dataset named DocuNet would not need to be dependent on specific document types or entity sets, making it universally applicable to all VDER tasks. Empowered by DocuNet, we present a lightweight multimodal architecture named UniFormer, which can learn a unified representation from text, layout, and image crops without needing extra visual pertaining. We experiment with our methods on popular VDER models in various settings and show the improvements when this massive dataset is incorporated with UniFormer on both classic entity retrieval and few-shot learning settings.