This paper investigates radar-assisted user acquisition for downlink multi-user multiple-input multiple-output (MIMO) transmission using Orthogonal Frequency Division Multiplexing (OFDM) signals. Specifically, we formulate a concise mathematical model for the user acquisition problem, where each user is characterized by its delay and beamspace response. Therefore, we propose a two-stage method for user acquisition, where the Multiple Signal Classification (MUSIC) algorithm is adopted for delay estimation, and then a least absolute shrinkage and selection operator (LASSO) is applied for estimating the user response in the beamspace. Furthermore, we also provide a comprehensive performance analysis of the considered problem based on the pair-wise error probability (PEP). Particularly, we show that the rank and the geometric mean of non-zero eigenvalues of the squared beamspace difference matrix determines the user acquisition performance. More importantly, we reveal that simultaneously probing multiple beams outperforms concentrating power on a specific beam direction in each time slot under the power constraint, when only limited OFDM symbols are transmitted. Our numerical results confirm our conclusions and also demonstrate a promising acquisition performance of the proposed two-stage method.