Greenhouse gas emissions have dramatically risen since the early 1900s with U.S. transportation generating 28% of the U.S' emissions. As such, there is interest in reducing transportation-related emissions. Specifically, sustainability research has sprouted around signalized intersections as intersections allow different streams of traffic to cross and change directions. Recent research has developed mixed traffic control eco-driving strategies at signalized intersections to decrease emissions. However, the inherent structure of a signalized intersection generates increased emissions by creating frequent acceleration/deceleration events, excessive idling from traffic congestion, and stop-and-go waves. Thus, we believe unsignalized intersections hold potential for further sustainability improvements. In this work, we provide an emissions analysis on unsignalized intersections with complex, real-world topologies and traffic demands where mixed traffic control strategies are employed by robot vehicles (RVs) to reduce waiting times and congestion. We find with at least 10% RV penetration rate, RVs generate less fuel consumption and NOx emissions than signalized intersections by up to 27% and 28%, respectively. With at least 30% RVs, CO and HC emissions are reduced by up to 42% and 43%, respectively. Additionally, RVs can reduce emissions across the whole network despite only employing their strategies at the intersections.