Several recent studies have investigated low-precision accumulation, reporting improvements in throughput, power, and area across various platforms. However, the accompanying proposals have only considered the quantization-aware training (QAT) paradigm, in which models are fine-tuned or trained from scratch with quantization in the loop. As models continue to grow in size, QAT techniques become increasingly more expensive, which has motivated the recent surge in post-training quantization (PTQ) research. To the best of our knowledge, ours marks the first formal study of accumulator-aware quantization in the PTQ setting. To bridge this gap, we introduce AXE, a practical framework of accumulator-aware extensions designed to endow overflow avoidance guarantees to existing layer-wise PTQ algorithms. We theoretically motivate AXE and demonstrate its flexibility by implementing it on top of two state-of-the-art PTQ algorithms: GPFQ and OPTQ. We further generalize AXE to support multi-stage accumulation for the first time, opening the door for full datapath optimization and scaling to large language models (LLMs). We evaluate AXE across image classification and language generation models, and observe significant improvements in the trade-off between accumulator bit width and model accuracy over baseline methods.