Face presentation attacks have become a major threat to face recognition systems and many countermeasures have been proposed in the past decade. However, most of them are devoted to 2D face presentation attacks, rather than 3D face masks. Unlike the real face, the 3D face mask is usually made of resin materials and has a smooth surface, resulting in reflectance differences. So, we propose a novel detection method for 3D face mask presentation attack by modeling reflectance differences based on intrinsic image analysis. In the proposed method, the face image is first processed with intrinsic image decomposition to compute its reflectance image. Then, the intensity distribution histograms are extracted from three orthogonal planes to represent the intensity differences of reflectance images between the real face and 3D face mask. After that, the 1D convolutional network is further used to capture the information for describing different materials or surfaces react differently to changes in illumination. Extensive experiments on the 3DMAD database demonstrate the effectiveness of our proposed method in distinguishing a face mask from the real one and show that the detection performance outperforms other state-of-the-art methods.