Multi-head latent attention (MLA) is designed to optimize KV cache memory through low-rank key-value joint compression. Rather than caching keys and values separately, MLA stores their compressed latent representations, reducing memory overhead while maintaining the performance. While MLA improves memory efficiency without compromising language model accuracy, its major limitation lies in its integration during the pre-training phase, requiring models to be trained from scratch. This raises a key question: can we use MLA's benefits fully or partially in models that have already been pre-trained with different attention mechanisms? In this paper, we propose X-EcoMLA to deploy post training distillation to enable the upcycling of Transformer-based attention into an efficient hybrid (i.e., combination of regular attention and MLA layers) or full MLA variant through lightweight post-training adaptation, bypassing the need for extensive pre-training. We demonstrate that leveraging the dark knowledge of a well-trained model can enhance training accuracy and enable extreme KV cache compression in MLA without compromising model performance. Our results show that using an 8B teacher model allows us to compress the KV cache size of the Llama3.2-1B-Inst baseline by 6.4x while preserving 100% of its average score across multiple tasks on the LM Harness Evaluation benchmark. This is achieved with only 3.6B training tokens and about 70 GPU hours on AMD MI300 GPUs, compared to the 370K GPU hours required for pre-training the Llama3.2-1B model.