The ambiguity at the boundaries of different semantic classes in point cloud semantic segmentation often leads to incorrect decisions in intelligent perception systems, such as autonomous driving. Hence, accurate delineation of the boundaries is crucial for improving safety in autonomous driving. A novel spatial inter-correlation enhancement and spatially-embedded feature fusion network (SIESEF-FusionNet) is proposed in this paper, enhancing spatial inter-correlation by combining inverse distance weighting and angular compensation to extract more beneficial spatial information without causing redundancy. Meanwhile, a new spatial adaptive pooling module is also designed, embedding enhanced spatial information into semantic features for strengthening the context-awareness of semantic features. Experimental results demonstrate that 83.7% mIoU and 97.8% OA are achieved by SIESEF-FusionNet on the Toronto3D dataset, with performance superior to other baseline methods. A value of 61.1% mIoU is reached on the semanticKITTI dataset, where a marked improvement in segmentation performance is observed. In addition, the effectiveness and plug-and-play capability of the proposed modules are further verified through ablation studies.