We propose an automata-theoretic approach for reinforcement learning (RL) under complex spatio-temporal constraints with time windows. The problem is formulated using a Markov decision process under a bounded temporal logic constraint. Different from existing RL methods that can eventually learn optimal policies satisfying such constraints, our proposed approach enforces a desired probability of constraint satisfaction throughout learning. This is achieved by translating the bounded temporal logic constraint into a total automaton and avoiding "unsafe" actions based on the available prior information regarding the transition probabilities, i.e., a pair of upper and lower bounds for each transition probability. We provide theoretical guarantees on the resulting probability of constraint satisfaction. We also provide numerical results in a scenario where a robot explores the environment to discover high-reward regions while fulfilling some periodic pick-up and delivery tasks that are encoded as temporal logic constraints.