The advent of Large Language Models (LLMs) has shown the potential to improve relevance and provide direct answers in web searches. However, challenges arise in validating the reliability of generated results and the credibility of contributing sources, due to the limitations of traditional information retrieval algorithms and the LLM hallucination problem. Aiming to create a "PageRank" for the LLM era, we strive to transform LLM into a relevant, responsible, and trustworthy searcher. We propose a novel generative retrieval framework leveraging the knowledge of LLMs to foster a direct link between queries and online sources. This framework consists of three core modules: Generator, Validator, and Optimizer, each focusing on generating trustworthy online sources, verifying source reliability, and refining unreliable sources, respectively. Extensive experiments and evaluations highlight our method's superior relevance, responsibility, and trustfulness against various SOTA methods.