Low-Rank Adaptation (LoRA) is a parameter-efficient fine-tuning method that has been widely adopted in various downstream applications of LLMs. Together with the Mixture-of-Expert (MoE) technique, fine-tuning approaches have shown remarkable improvements in model capability. However, the coordination of multiple experts in existing studies solely relies on the weights assigned by the simple router function. Lack of communication and collaboration among experts exacerbate the instability of LLMs due to the imbalance load problem of MoE. To address this issue, we propose a novel MoE graph-based LLM fine-tuning framework GraphLoRA, in which a graph router function is designed to capture the collaboration signals among experts by graph neural networks (GNNs). GraphLoRA enables all experts to understand input knowledge and share information from neighbor experts by aggregating operations. Besides, to enhance each expert's capability and their collaborations, we design two novel coordination strategies: the Poisson distribution-based distinction strategy and the Normal distribution-based load balance strategy. Extensive experiments on four real-world datasets demonstrate the effectiveness of our GraphLoRA in parameter-efficient fine-tuning of LLMs, showing the benefits of facilitating collaborations of multiple experts in the graph router of GraphLoRA.