Despite tremendous advancements, current state-of-the-art Vision-Language Models (VLMs) are still far from perfect. They tend to hallucinate and may generate biased responses. In such circumstances, having a way to assess the reliability of a given response generated by a VLM is quite useful. Existing methods, such as estimating uncertainty using answer likelihoods or prompt-based confidence generation, often suffer from overconfidence. Other methods use self-consistency comparison but are affected by confirmation biases. To alleviate these, we propose \textbf{De}compose and \textbf{C}ompare \textbf{C}onsistency (\texttt{DeCC}) for reliability measurement. By comparing the consistency between the direct answer generated using the VLM's internal reasoning process, and the indirect answers obtained by decomposing the question into sub-questions and reasoning over the sub-answers produced by the VLM, \texttt{DeCC} measures the reliability of VLM's direct answer. Experiments across six vision-language tasks with three VLMs show \texttt{DeCC}'s reliability estimation achieves better correlation with task accuracy compared to the existing methods.