Longitudinal network data are essential for analyzing political, economic, and social systems and processes. In political science, these datasets are often generated through human annotation or supervised machine learning applied to evolving corpora. However, as semantic contexts shift over time, inferring dynamic interaction types on emerging issues among a diverse set of entities poses significant challenges, particularly in maintaining timely and consistent annotations. This paper presents the Expert-Augmented LLM Annotation (EALA) approach, which leverages Large Language Models (LLMs) in combination with historically annotated data and expert-constructed codebooks to extrapolate and extend datasets into future periods. We evaluate the performance and reliability of EALA using a dataset of climate negotiations. Our findings demonstrate that EALA effectively predicts nuanced interactions between negotiation parties and captures the evolution of topics over time. At the same time, we identify several limitations inherent to LLM-based annotation, highlighting areas for further improvement. Given the wide availability of codebooks and annotated datasets, EALA holds substantial promise for advancing research in political science and beyond.