Large Language Models (LLMs) can enhance the credibility and verifiability by generating text with citations. However, existing tasks and evaluation methods are predominantly limited to sentence-level statement, neglecting the significance of positional fine-grained citations that can appear anywhere within sentences. To facilitate further exploration of the fine-grained citation generation, we propose ALiiCE, the first automatic evaluation framework for this task. Our framework first parses the sentence claim into atomic claims via dependency analysis and then calculates citation quality at the atomic claim level. ALiiCE introduces three novel metrics for positional fined-grained citation quality assessment, including positional fine-grained citation recall and precision, and coefficient of variation of citation positions. We evaluate the positional fine-grained citation generation performance of several LLMs on two long-form QA datasets. Our experiments and analyses demonstrate the effectiveness and reasonableness of ALiiCE. The results also indicate that existing LLMs still struggle to provide positional fine-grained citations.