Fine-grained radio map presents communication parameters of interest, e.g., received signal strength, at every point across a large geographical region. It can be leveraged to improve the efficiency of spectrum utilization for a large area, particularly critical for the unlicensed WiFi spectrum. The problem of fine-grained radio map estimation is to utilize radio samples collected by sparsely distributed sensors to infer the map. This problem is challenging due to the ultra-low sampling rate, where the number of available samples is far less than the fine-grained resolution required for radio map estimation. We propose WiFi-Diffusion -- a novel generative framework for achieving fine-grained WiFi radio map estimation using diffusion models. WiFi-Diffusion employs the creative power of generative AI to address the ultra-low sampling rate challenge and consists of three blocks: 1) a boost block, using prior information such as the layout of obstacles to optimize the diffusion model; 2) a generation block, leveraging the diffusion model to generate a candidate set of radio maps; and 3) an election block, utilizing the radio propagation model as a guide to find the best radio map from the candidate set. Extensive simulations demonstrate that 1) the fine-grained radio map generated by WiFi-Diffusion is ten times better than those produced by state-of-the-art (SOTA) when they use the same ultra-low sampling rate; and 2) WiFi-Diffusion achieves comparable fine-grained radio map quality with only one-fifth of the sampling rate required by SOTA.