Large Language Models (LLMs) have demonstrated significant potential in automating software testing, specifically in generating unit test cases. However, the validation of LLM-generated test cases remains a challenge, particularly when the ground truth is unavailable. This paper introduces VALTEST, a novel framework designed to automatically validate test cases generated by LLMs by leveraging token probabilities. We evaluate VALTEST using nine test suites generated from three datasets (HumanEval, MBPP, and LeetCode) across three LLMs (GPT-4o, GPT-3.5-turbo, and LLama3.1 8b). By extracting statistical features from token probabilities, we train a machine learning model to predict test case validity. VALTEST increases the validity rate of test cases by 6.2% to 24%, depending on the dataset and LLM. Our results suggest that token probabilities are reliable indicators for distinguishing between valid and invalid test cases, which provides a robust solution for improving the correctness of LLM-generated test cases in software testing. In addition, we found that replacing the identified invalid test cases by VALTEST, using a Chain-of-Thought prompting results in a more effective test suite while keeping the high validity rates.