Deep subspace clustering methods are now prominent in clustering, typically using fully connected networks and a self-representation loss function. However, these methods often struggle with overfitting and lack interpretability. In this paper, we explore an alternative clustering approach based on deep unfolding. By unfolding iterative optimization methods into neural networks, this approach offers enhanced interpretability and reliability compared to data-driven deep learning methods, and greater adaptability and generalization than model-based approaches. Hence, unfolding has become widely used in inverse imaging problems, such as image restoration, reconstruction, and super-resolution, but has not been sufficiently explored yet in the context of clustering. In this work, we introduce an innovative clustering architecture for hyperspectral images (HSI) by unfolding an iterative solver based on the Alternating Direction Method of Multipliers (ADMM) for sparse subspace clustering. To our knowledge, this is the first attempt to apply unfolding ADMM for computing the self-representation matrix in subspace clustering. Moreover, our approach captures well the structural characteristics of HSI data by employing the K nearest neighbors algorithm as part of a structure preservation module. Experimental evaluation of three established HSI datasets shows clearly the potential of the unfolding approach in HSI clustering and even demonstrates superior performance compared to state-of-the-art techniques.