Probabilistic artificial neural networks offer intriguing prospects for enabling the uncertainty of artificial intelligence methods to be described explicitly in their function; however, the development of techniques that quantify uncertainty by well-understood methods such as Monte Carlo sampling has been limited by the high costs of stochastic sampling on deterministic computing hardware. Emerging computing systems that are amenable to hardware-level probabilistic computing, such as those that leverage stochastic devices, may make probabilistic neural networks more feasible in the not-too-distant future. This paper describes the scANN technique -- \textit{sampling (by coinflips) artificial neural networks} -- which enables neural networks to be sampled directly by treating the weights as Bernoulli coin flips. This method is natively well suited for probabilistic computing techniques that focus on tunable stochastic devices, nearly matches fully deterministic performance while also describing the uncertainty of correct and incorrect neural network outputs.