This work explores the clustering of wireless users by examining the distances between their channel covariance matrices, which reside on the Riemannian manifold of positive definite matrices. Specifically, we consider an estimator of the Log-Euclidean distance between multiple sample covariance matrices (SCMs) consistent when the number of samples and the observation size grow unbounded at the same rate. Within the context of multi-user MIMO (MU-MIMO) wireless communication systems, we develop a statistical framework that allows to accurate predictions of the clustering algorithm's performance under realistic conditions. Specifically, we present a central limit theorem that establishes the asymptotic Gaussianity of the consistent estimator of the log-Euclidean distance computed over two sample covariance matrices.