The widespread use of face recognition technology has given rise to privacy concerns, as many individuals are worried about the collection and utilization of their facial data. To address these concerns, researchers are actively exploring the concept of ``unlearnable examples", by adding imperceptible perturbation to data in the model training stage, which aims to prevent the model from learning discriminate features of the target face. However, current methods are inefficient and cannot guarantee transferability and robustness at the same time, causing impracticality in the real world. To remedy it, we propose a novel method called Segue: Side-information guided generative unlearnable examples. Specifically, we leverage a once-trained multiple-used model to generate the desired perturbation rather than the time-consuming gradient-based method. To improve transferability, we introduce side information such as true labels and pseudo labels, which are inherently consistent across different scenarios. For robustness enhancement, a distortion layer is integrated into the training pipeline. Extensive experiments demonstrate that the proposed Segue is much faster than previous methods (1000$\times$) and achieves transferable effectiveness across different datasets and model architectures. Furthermore, it can resist JPEG compression, adversarial training, and some standard data augmentations.