Mixed-precision computing, a widely applied technique in AI, offers a larger trade-off space between accuracy and efficiency. The recent purposed Mixed-Precision Over-the-Air Federated Learning (MP-OTA-FL) enables clients to operate at appropriate precision levels based on their heterogeneous hardware, taking advantages of the larger trade-off space while covering the quantization overheads in the mixed-precision modulation scheme for the OTA aggregation process. A key to further exploring the potential of the MP-OTA-FL framework is the optimization of client precision levels. The choice of precision level hinges on multifaceted factors including hardware capability, potential client contribution, and user satisfaction, among which factors can be difficult to define or quantify. In this paper, we propose a RAG-based User Profiling for precision planning framework that integrates retrieval-augmented LLMs and dynamic client profiling to optimize satisfaction and contributions. This includes a hybrid interface for gathering device/user insights and an RAG database storing historical quantization decisions with feedback. Experiments show that our method boosts satisfaction, energy savings, and global model accuracy in MP-OTA-FL systems.