In this work, the concept of optical identification (OI) is introduced for the first time. The OI assigns an optical fingerprint and the corresponding digital signature to each sub-system of the network and estimates its reliability in different measures. We highlight the large potential applications of OI as a physical layer approach for security, identification, authentication, and monitoring purposes. To identify most of the sub-systems of a network, we propose to use the Rayleigh backscattering pattern, which is an optical physical unclonable function and allows to achieve OI with a simple procedure and without additional devices. The application of OI to fiber and path identification in a network, and to the authentication of the users in a quantum key distribution system are described.