Recently, Kirkpatrick et al. [ALT 2019] and Fallat et al. [JMLR 2023] introduced non-clashing teaching and showed it to be the most efficient machine teaching model satisfying the benchmark for collusion-avoidance set by Goldman and Mathias. A teaching map $T$ for a concept class $\cal{C}$ assigns a (teaching) set $T(C)$ of examples to each concept $C \in \cal{C}$. A teaching map is non-clashing if no pair of concepts are consistent with the union of their teaching sets. The size of a non-clashing teaching map (NCTM) $T$ is the maximum size of a $T(C)$, $C \in \cal{C}$. The non-clashing teaching dimension NCTD$(\cal{C})$ of $\cal{C}$ is the minimum size of an NCTM for $\cal{C}$. NCTM$^+$ and NCTD$^+(\cal{C})$ are defined analogously, except the teacher may only use positive examples. We study NCTMs and NCTM$^+$s for the concept class $\mathcal{B}(G)$ consisting of all balls of a graph $G$. We show that the associated decision problem {\sc B-NCTD$^+$} for NCTD$^+$ is NP-complete in split, co-bipartite, and bipartite graphs. Surprisingly, we even prove that, unless the ETH fails, {\sc B-NCTD$^+$} does not admit an algorithm running in time $2^{2^{o(vc)}}\cdot n^{O(1)}$, nor a kernelization algorithm outputting a kernel with $2^{o(vc)}$ vertices, where vc is the vertex cover number of $G$. These are extremely rare results: it is only the second (fourth, resp.) problem in NP to admit a double-exponential lower bound parameterized by vc (treewidth, resp.), and only one of very few problems to admit an ETH-based conditional lower bound on the number of vertices in a kernel. We complement these lower bounds with matching upper bounds. For trees, interval graphs, cycles, and trees of cycles, we derive NCTM$^+$s or NCTMs for $\mathcal{B}(G)$ of size proportional to its VC-dimension. For Gromov-hyperbolic graphs, we design an approximate NCTM$^+$ for $\mathcal{B}(G)$ of size 2.