Systolic arrays are a prominent choice for deep neural network (DNN) accelerators because they offer parallelism and efficient data reuse. Improving the reliability of DNN accelerators is crucial as hardware faults can degrade the accuracy of DNN inferencing. Systolic arrays make use of a large number of processing elements (PEs) for parallel processing, but when one PE is faulty, the error propagates and affects the outcomes of downstream PEs. Due to the large number of PEs, the cost associated with implementing hardware-based runtime monitoring of every single PE is infeasible. We present a solution to optimize the placement of hardware monitors within systolic arrays. We first prove that $2N-1$ monitors are needed to localize a single faulty PE and we also derive the monitor placement. We show that a second placement optimization problem, which minimizes the set of candidate faulty PEs for a given number of monitors, is NP-hard. Therefore, we propose a heuristic approach to balance the reliability and hardware resource utilization in DNN accelerators when number of monitors is limited. Experimental evaluation shows that to localize a single faulty PE, an area overhead of only 0.33% is incurred for a $256\times 256$ systolic array.