We develop a fitted value iteration (FVI) method to compute bicausal optimal transport (OT) where couplings have an adapted structure. Based on the dynamic programming formulation, FVI adopts a function class to approximate the value functions in bicausal OT. Under the concentrability condition and approximate completeness assumption, we prove the sample complexity using (local) Rademacher complexity. Furthermore, we demonstrate that multilayer neural networks with appropriate structures satisfy the crucial assumptions required in sample complexity proofs. Numerical experiments reveal that FVI outperforms linear programming and adapted Sinkhorn methods in scalability as the time horizon increases, while still maintaining acceptable accuracy.