Platooning of connected and autonomous vehicles (CAVs) plays a vital role in modernizing highways, ushering in enhanced efficiency and safety. This paper explores the significance of platooning in smart highways, employing a coupled partial differential equation (PDE) and ordinary differential equation (ODE) model to elucidate the complex interaction between bulk traffic flow and CAV platoons. Our study focuses on developing a Dyna-style planning and learning framework tailored for platoon control, with a specific goal of reducing fuel consumption. By harnessing the coupled PDE-ODE model, we improve data efficiency in Dyna-style learning through virtual experiences. Simulation results validate the effectiveness of our macroscopic model in modeling platoons within mixed-autonomy settings, demonstrating a notable $10.11\%$ reduction in vehicular fuel consumption compared to conventional approaches.