In today's era, autonomous vehicles demand a safety level on par with aircraft. Taking a cue from the aerospace industry, which relies on redundancy to achieve high reliability, the automotive sector can also leverage this concept by building redundancy in V2X (Vehicle-to-Everything) technologies. Given the current lack of reliable V2X technologies, this idea is particularly promising. By deploying multiple RATs (Radio Access Technologies) in parallel, the ongoing debate over the standard technology for future vehicles can be put to rest. However, coordinating multiple communication technologies is a complex task due to dynamic, time-varying channels and varying traffic conditions. This paper addresses the vertical handover problem in V2X using Deep Reinforcement Learning (DRL) algorithms. The goal is to assist vehicles in selecting the most appropriate V2X technology (DSRC/V-VLC) in a serpentine environment. The results show that the benchmarked algorithms outperform the current state-of-the-art approaches in terms of redundancy and usage rate of V-VLC headlights. This result is a significant reduction in communication costs while maintaining a high level of reliability. These results provide strong evidence for integrating advanced DRL decision mechanisms into the architecture as a promising approach to solving the vertical handover problem in V2X.