Confidence assessments of semantic segmentation algorithms in remote sensing are important. It is a desirable property of models to a priori know if they produce an incorrect output. Evaluations of the confidence assigned to the estimates of models for the task of classification in Earth Observation (EO) are crucial as they can be used to achieve improved semantic segmentation performance and prevent high error rates during inference and deployment. The model we develop, the Confidence Assessments of classification algorithms for Semantic segmentation (CAS) model, performs confidence evaluations at both the segment and pixel levels, and outputs both labels and confidence. The outcome of this work has important applications. The main application is the evaluation of EO Foundation Models on semantic segmentation downstream tasks, in particular land cover classification using satellite Copernicus Sentinel-2 data. The evaluation shows that the proposed model is effective and outperforms other alternative baseline models.