AI models make mistakes when recognizing images-whether in-domain, out-of-domain, or adversarial. Predicting these errors is critical for improving system reliability, reducing costly mistakes, and enabling proactive corrections in real-world applications such as healthcare, finance, and autonomous systems. However, understanding what mistakes AI models make, why they occur, and how to predict them remains an open challenge. Here, we conduct comprehensive empirical evaluations using a "mentor" model-a deep neural network designed to predict another model's errors. Our findings show that the mentor model excels at learning from a mentee's mistakes on adversarial images with small perturbations and generalizes effectively to predict in-domain and out-of-domain errors of the mentee. Additionally, transformer-based mentor models excel at predicting errors across various mentee architectures. Subsequently, we draw insights from these observations and develop an "oracle" mentor model, dubbed SuperMentor, that achieves 78% accuracy in predicting errors across different error types. Our error prediction framework paves the way for future research on anticipating and correcting AI model behaviours, ultimately increasing trust in AI systems. All code, models, and data will be made publicly available.