This letter proposes a high-resolution channel estimation for reconfigurable intelligent surface (RIS)-assisted communication networks. We exploit the inherent geometrical structure of the Terahertz propagation channel, including the antenna array geometries at the base station, the RIS, and the user equipment to design a tensor-based high-resolution channel estimator, referred to as the higher-dimensional rank-one approximations (HDR) method. By exploiting the geometrical structure of the combined base station-RIS-user equipment channel, the proposed HDR estimator recasts parametric channel estimation as a single sixth-order rank-one tensor approximation problem, which can be efficiently solved using higher-order singular value decomposition to deliver parallel estimates of each channel component vector. Numerical results show that the proposed method provides significantly more accurate parameter estimates compared to the competing state-of-the-art Khatri-Rao factorization and least squares methods. The HDR method also leads to higher spectral efficiency than its competitors, especially in the low signal-to-noise ratio regime, while having similar computational complexity as the classical least squares method.