As core thermal power generation equipment, steam turbines incur significant expenses and adverse effects on operation when facing interruptions like downtime, maintenance, and damage. Accurate anomaly detection is the prerequisite for ensuring the safe and stable operation of steam turbines. However, challenges in steam turbine anomaly detection, including inherent anomalies, lack of temporal information analysis, and high-dimensional data complexity, limit the effectiveness of existing methods. To address these challenges, we proposed an Enhanced Long Short-Term Memory Variational Autoencoder using Deep Advanced Features and Gaussian Mixture Model (ELSTMVAE-DAF-GMM) for precise unsupervised anomaly detection in unlabeled datasets. Specifically, LSTMVAE, integrating LSTM with VAE, was used to project high-dimensional time-series data to a low-dimensional phase space. The Deep Autoencoder-Local Outlier Factor (DAE-LOF) sample selection mechanism was used to eliminate inherent anomalies during training, further improving the model's precision and reliability. The novel deep advanced features (DAF) hybridize latent embeddings and reconstruction discrepancies from the LSTMVAE model and provide a more comprehensive data representation within a continuous and structured phase space, significantly enhancing anomaly detection by synergizing temporal dynamics with data pattern variations. These DAF were incorporated into GMM to ensure robust and effective unsupervised anomaly detection. We utilized real operating data from industry steam turbines and conducted both comparison and ablation experiments, demonstrating superior anomaly detection outcomes characterized by high accuracy and minimal false alarm rates compared with existing methods.