Spectral Unmixing Comparison with Sparse, Iterative and Mixed Integer Programming Models

Hyperspectral unmixing is the analytical process of determining the pure materials and estimating the proportions of such materials composed within an observed mixed pixel spectrum. We can unmix mixed pixel spectra using linear and nonlinear mixture models. Ordinary least squares (OLS) regression serves as the foundation for many linear mixture models employed in Hyperspectral Image analysis. Though variations of OLS are implemented, studies rarely address the underlying assumptions that affect results. This paper provides an in depth discussion on the assumptions inherently endorsed by the application of OLS regression. We also examine variations of OLS models stemming from highly effective approaches in spectral unmixing -- sparse regression, iterative feature search strategies and Mathematical programming. These variations are compared to a novel unmixing approach called HySUDeB. We evaluated each approach's performance by computing the average error and precision of each model. Additionally, we provide a taxonomy of the molecular structure of each mineral to derive further understanding into the detection of the target materials.