To comprehensively assess the capacity of current models for complex reasoning, it is crucial to assess their step-by-step reasoning in a scalable manner. Established reference-based evaluation metrics rely on human-annotated reasoning chains to assess the model-derived chains. However, such ``gold-standard'' human-written reasoning chains may not be unique and their acquisition is often labor-intensive. Existing reference-free reasoning metrics eliminate the need for human-crafted reasoning chains as references, but they typically require fine-tuning on datasets with human-derived reasoning chains, which complicates the process and raises concerns regarding generalizability across diverse datasets. To address these challenges, we harness GPT-4 to automatically evaluate reasoning chain quality, obviating the need for human-crafted references. Leveraging the Socratic method, we devise tailored prompts to enhance reference-free reasoning evaluation, which we term SocREval (Socratic method for Reasoning Evaluation). Empirical results from four human annotated datasets reveal that SocREval significantly improves GPT-4's performance, surpassing existing reference-free and reference-based reasoning evaluation metrics. Beyond its demonstrated efficacy, our proposed framework, large language models (LLMs) with the Socratic method, proves to be both cost-efficient and robust to prompt writing and example selection, as substantiated by our in-depth analysis.