Reinforcement learning (RL) algorithms can enable high-maneuverability in unmanned aerial vehicles (MAVs), but transferring them from simulation to real-world use is challenging. Variable-pitch propeller (VPP) MAVs offer greater agility, yet their complex dynamics complicate the sim-to-real transfer. This paper introduces a novel RL framework to overcome these challenges, enabling VPP MAVs to perform advanced aerial maneuvers in real-world settings. Our approach includes real-to-sim transfer techniques-such as system identification, domain randomization, and curriculum learning to create robust training simulations and a sim-to-real transfer strategy combining a cascade control system with a fast-response low-level controller for reliable deployment. Results demonstrate the effectiveness of this framework in achieving zero-shot deployment, enabling MAVs to perform complex maneuvers such as flips and wall-backtracking.