The ability to accurately estimate room impulse responses (RIRs) is integral to many applications of spatial audio processing. Regrettably, estimating the RIR using ambient signals, such as speech or music, remains a challenging problem due to, e.g., low signal-to-noise ratios, finite sample lengths, and poor spectral excitation. Commonly, in order to improve the conditioning of the estimation problem, priors are placed on the amplitudes of the RIR. Although serving as a regularizer, this type of prior is generally not useful when only approximate knowledge of the delay structure is available, which, for example, is the case when the prior is a simulated RIR from an approximation of the room geometry. In this work, we target the delay structure itself, constructing a prior based on the concept of optimal transport. As illustrated using both simulated and measured data, the resulting method is able to beneficially incorporate information even from simple simulation models, displaying considerable robustness to perturbations in the assumed room dimensions and its temperature.