In this paper reinforcement learning with binary vector actions was investigated. We suggest an effective architecture of the neural networks for approximating an action-value function with binary vector actions. The proposed architecture approximates the action-value function by a linear function with respect to the action vector, but is still non-linear with respect to the state input. We show that this approximation method enables the efficient calculation of greedy action selection and softmax action selection. Using this architecture, we suggest an online algorithm based on Q-learning. The empirical results in the grid world and the blocker task suggest that our approximation architecture would be effective for the RL problems with large discrete action sets.