The task of semantic role labeling (SRL) is dedicated to finding the predicate-argument structure. Previous works on SRL are mostly supervised and do not consider the difficulty in labeling each example which can be very expensive and time-consuming. In this paper, we present the first neural unsupervised model for SRL. To decompose the task as two argument related subtasks, identification and clustering, we propose a pipeline that correspondingly consists of two neural modules. First, we train a neural model on two syntax-aware statistically developed rules. The neural model gets the relevance signal for each token in a sentence, to feed into a BiLSTM, and then an adversarial layer for noise-adding and classifying simultaneously, thus enabling the model to learn the semantic structure of a sentence. Then we propose another neural model for argument role clustering, which is done through clustering the learned argument embeddings biased towards their dependency relations. Experiments on CoNLL-2009 English dataset demonstrate that our model outperforms previous state-of-the-art baseline in terms of non-neural models for argument identification and classification.