Domain generalization achieves fault diagnosis on unseen modes. In process industrial systems, fault samples are limited, and only single-mode fault data can be obtained. Extracting domain-invariant fault features from single-mode data for unseen mode fault diagnosis poses challenges. Existing methods utilize a generator module to simulate samples of unseen modes. However, multi-mode samples contain complex spatiotemporal information, which brings significant difficulties to accurate sample generation. Therefore, double gradient reversal network (DGRN) is proposed. First, the model is pre-trained to acquire fault knowledge from the single seen mode. Then, pseudo-fault feature generation strategy is designed by Adaptive instance normalization, to simulate fault features of unseen mode. The dual adversarial training strategy is created to enhance the diversity of pseudo-fault features, which models unseen modes with significant distribution differences. Subsequently, domain-invariant feature extraction strategy is constructed by contrastive learning and adversarial learning. This strategy extracts common features of faults and helps multi-mode fault diagnosis. Finally, the experiments were conducted on Tennessee Eastman process and continuous stirred-tank reactor. The experiments demonstrate that DGRN achieves high classification accuracy on unseen modes while maintaining a small model size.