Connected autonomous vehicles (CAV) constitute an important application of future-oriented traffic management .A vehicular system dominated by fully autonomous vehicles requires a robust and efficient vehicle-to-everything (V2X) infrastructure that will provide sturdy connection of vehicles in both short and long distances for a large number of devices, requiring high spectral efficiency (SE). Power domain non-orthogonal multiple access (PD-NOMA) technique has the potential to provide the required high SE levels. In this paper, a vehicular PD-NOMA testbed is implemented using software defined radio (SDR) nodes. The main concerns and their corresponding solutions arising from the implementation are highlighted. The bit error rates(BER) of vehicles with different channel conditions are measured for mobile and stationary cases. The extent of the estimation errors on the success rate beyond the idealized theoretical analysis view is investigated and the approaches to alleviate these errors are discussed. Finally, our perspective on possible PD-NOMA based CAV deployment scenarios is presented in terms of performance constraints and expectancy along with the overlooked open issues.