The Fourth Industrial Revolution (4IR) is transforming the way we live and work, and education is no exception. To cope with the challenges of 4IR, there is a need for innovative and sustainable teaching and learning tools. AI and block chain technologies hold great promise in this regard, with potential benefits such as personalized learning, secure credentialing, and decentralized learning networks. This paper presents a review of existing research on AI and block chain in education, analyzing case studies and exploring the potential benefits and challenges of these technologies. The paper also suggests a unique model for integrating AI and block chain into sustainable teaching and learning practices. Future research directions are discussed, including the need for more empirical studies and the exploration of ethical and social implications. The key summary of this discussion is that, by enhancing accessibility, efficacy, and security in education, AI and blockchain have the potential to revolutionise the field. In order to ensure that students can benefit from these potentially game-changing technologies as technology develops, it will be crucial to find ways to harness its power while minimising hazards. Overall, this paper highlights the potential of AI and block chain as sustainable tools for teaching and learning in the 4IR era and their respective advantages, issues and future prospects have been discussed in this writing.